منابع مشابه
Thermodynamics of Polymer Solutions
Most of the synthetic compounds are prepared and processed in the liquid state, i.e. in solution or in the molten state. Detailed knowledge on this state is therefore indispensable. In particular it is essential to know the limits of complete miscibility with a low molecular weight solvent as a function of temperature, pressure and composition. Furthermore it is often mandatory to be acquainted...
متن کاملTurbulence of polymer solutions.
We investigate high-Reynolds-number turbulence in dilute polymer solutions. We show the existence of a critical value of the Reynolds number, which separates two different regimes. In the first regime, below the transition, the influence of the polymer molecules on the flow is negligible, so they can be regarded as passively embedded in the flow. This case admits a detailed investigation of the...
متن کاملViscoelastic properties of polymer solutions.
In a concentrated polymer solution, the entanglement of long-chain molecules results in a transient network structure, to which may be attributed certain aspects of the viscoelastic behavior of such a system. A suitable mechanical model for representing this network as a first approximation is a retarded Maxwell element with one spring and two dashpots. Experimental measurements of mechanical p...
متن کاملSoft Confinement for Polymer Solutions
As a model of soft confinement for polymers, we investigated equilibrium shapes of a flexible vesicle that contains a phase-separating polymer solution. To simulate such a system, we combined the phase field theory (PFT) for the vesicle and the self-consistent field theory (SCFT) for the polymer solution. We observed a transition from a symmetric prolate shape of the vesicle to an asymmetric pe...
متن کامل0 Polydisperse star polymer solutions
We analyze the effect of polydispersity in the arm number on the effective interactions , structural correlations and the phase behavior of star polymers in a good solvent. The effective interaction potential between two star polymers with different arm numbers is derived using scaling theory. The resulting expression is tested against monomer-resolved molecular dynamics simulations. We find th...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1957
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed034pa280.1